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Kim, Jin Young
Next Generation Energy Lab.
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Single Component Organic Solar Cells Based on Oligothiophene-Fullerene Conjugate

Author(s)
Thanh Luan NguyenLee, Tack HoGautam, BhojPark, Song YiGundogdu, KenanKim, Jin YoungWoo, Han Young
Issued Date
2017-10
DOI
10.1002/adfm.201702474
URI
https://scholarworks.unist.ac.kr/handle/201301/22938
Fulltext
http://onlinelibrary.wiley.com/doi/10.1002/adfm.201702474/abstract
Citation
ADVANCED FUNCTIONAL MATERIALS, v.27, no.39, pp.1702474
Abstract
A new donor (D)-acceptor (A) conjugate, benzodithiophene-rhodanine-[6,6]-phenyl-C-61 butyric acid methyl ester (BDTRh-PCBM) comprising three covalently linked blocks, one of p-type oligothiophene containing BDTRh moieties and two of n-type PCBM, is designed and synthesized. A single component organic solar cell (SCOSC) fabricated from BDTRh-PCBM exhibits the power conversion efficiency (PCE) of 2.44% and maximum external quantum efficiency of 46%, which are the highest among the reported efficiencies so far. The SCOSC device shows efficient charge transfer (CT, approximate to 300 fs) and smaller CT energy loss, resulting in the higher open-circuit voltage of 0.97 V, compared to the binary blend (BDTRh:PCBM). Because of the integration of the donor and acceptor in a single molecule, BDTRh-PCBM has a specific D-A arrangement with less energetic disorder and reorganization energy than blend systems. In addition, the SCOSC device shows excellent device and morphological stabilities, showing no degradation of PCE at 80 degrees C for 100 h. The SCOSC approach may suggest a great way to suppress the large phase segregation of donor and acceptor domains with better morphological stability compared to the blend device.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1616-301X
Keyword (Author)
charge transferenergy lossorganic photovoltaicssingle component solar cellstransient absorption spectroscopy
Keyword
MORPHOLOGY CONTROLPOLYMEREFFICIENCYPHOTOVOLTAICSACCEPTORMOLECULEDYADENERGYORIENTATIONGENERATION

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