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- Lee, Chang Young
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Direct diversification of unmasked quinazolin-4(3: H)-ones through orthogonal reactivity modulation
- Author(s)
- Lee, Jae Bin, Kang, Mi Eun, Kim, Joohee, Lee, Chang Young, Kee, Jung-Min, Myung, Kyungjae, Park, Jang-Ung, Hong, Sung You
- Issued Date
- 2017-09
- Citation
- CHEMICAL COMMUNICATIONS, v.53, no.75, pp.10394 - 10397
- Abstract
- Here we report a set of direct functionalization methods of unmasked 2-phenylquinazolin-4(3H)-ones, a privileged alkaloid core, without the installation/removal event of protecting groups or exogenous coordinating moieties. Divergent pathways were modulated with transition-metal catalysts by suppressing competitive reactivities, leading to N-arylation, annulative π-extension, or C-H fluorination.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1359-7345
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