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- Cho, Jaeheung
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Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect
- Author(s)
- Derrick, Jeffrey S, Kim, Yujeong, Tak, Hyeonwoo, Park, Kiyoung, Cho, Jaeheung, Kim, Sun Hee, Lim, Mi Hee
- Issued Date
- 2017-10
- Citation
- DALTON TRANSACTIONS, v.46, no.39, pp.13166 - 13170
- Abstract
- Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)]2+ complex via an anion effect. Our crystallographic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)2 produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)2.
- Publisher
- ROYAL SOC CHEMISTRY
- ISSN
- 1477-9226
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