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DC Field | Value | Language |
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dc.citation.endPage | 8265 | - |
dc.citation.number | 32 | - |
dc.citation.startPage | 8256 | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY C | - |
dc.citation.volume | 5 | - |
dc.contributor.author | Manh Linh Nguyen | - |
dc.contributor.author | Shin, Tae Joo | - |
dc.contributor.author | Kim, Ho-Joong | - |
dc.contributor.author | Cho, Byoung-Ki | - |
dc.date.accessioned | 2023-12-21T22:06:23Z | - |
dc.date.available | 2023-12-21T22:06:23Z | - |
dc.date.created | 2017-09-08 | - |
dc.date.issued | 2017-08 | - |
dc.description.abstract | We report the electric-field (E-field)-assisted orientation of a bent-core liquid crystal (LC) based on the polar 1,2,3-triazolyl group. The LC exhibited a hexagonal columnar (COLhex) phase at ambient temperature, which transformed into a disordered columnar (COLdis) phase with short-range correlation upon heating. Dielectric relaxation spectroscopy and switching studies revealed that the aromatic cores could undergo in-plane rotation (a-relaxation) in the COLhex phase, while R-relaxation allowing the reorientation of the triazolyl units along the E-field direction occurred in the COLdis phase. Infrared spectroscopy confirmed that the hydrogen-bonding interactions between triazolyl units along the columnar axis affected the molecular motion. Based on the dynamics studies, two columnar alignment methods under E-fields, i.e., an isothermal method in the COLhex phase and a cooling method from the COLdis to COLhex phase were examined. Both methods give high-quality oriented columnar thin films. In particular, the cooling method requires less time (only 1 min) and a weaker E-field (10 V mu m(-1)), and therefore, it could be applied to the alignment of a bulk-level film (thickness: 260 mm). The successful orientation could be verified by in situ X-ray diffraction analysis under an E-field. The current-voltage curves before and after the alignment indicated that the orientation process enhanced electric conduction. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY C, v.5, no.32, pp.8256 - 8265 | - |
dc.identifier.doi | 10.1039/c7tc02710a | - |
dc.identifier.issn | 2050-7526 | - |
dc.identifier.scopusid | 2-s2.0-85027576048 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/22677 | - |
dc.identifier.url | http://pubs.rsc.org/en/Content/ArticleLanding/2017/TC/C7TC02710A#!divAbstract | - |
dc.identifier.wosid | 000407815800030 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Oriented columnar films of a polar 1,2,3-triazole-based liquid crystal prepared by applying an electric field | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary; Physics, Applied | - |
dc.relation.journalResearchArea | Materials Science; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | THIN-FILMS | - |
dc.subject.keywordPlus | LARGE-AREA | - |
dc.subject.keywordPlus | MESOPHASES | - |
dc.subject.keywordPlus | MOLECULES | - |
dc.subject.keywordPlus | TRANSPORT | - |
dc.subject.keywordPlus | PHASE | - |
dc.subject.keywordPlus | BLOCK | - |
dc.subject.keywordPlus | LUMINESCENCE | - |
dc.subject.keywordPlus | FLUORESCENT | - |
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