File Download

There are no files associated with this item.

  • Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
Related Researcher

문회리

Moon, Hoi Ri
Functional Inorganic Nanomaterials Lab for Energy
Read More

Views & Downloads

Detailed Information

Cited time in webofscience Cited time in scopus
Metadata Downloads

Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand

Author(s)
Lee, Jae HwaPark, SungbinJeoung, SungeunMoon, Hoi Ri
Issued Date
2017-07
DOI
10.1039/c6ce02652d
URI
https://scholarworks.unist.ac.kr/handle/201301/22427
Fulltext
http://pubs.rsc.org/en/Content/ArticleLanding/2017/CE/C6CE02652D#!divAbstract
Citation
CRYSTENGCOMM, v.19, no.27, pp.3719 - 3722
Abstract
A 2D interdigitated [Ni2(adipate)2(spy)4(H2O)2] (spy = 4-styrylpyridine) was transformed to a 3D coordination polymer through [2 + 2] photodimerization between the olefin bonds in spy upon UV-irradiation in a single-crystal-to-single-crystal (SC-SC) manner. During this transformation, a coexisting flexible adipate ligand changes its conformation, and helps in withstanding the conversion strain and retaining the single crystallinity.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1466-8033
Keyword
SOLID-STATE PHOTODIMERIZATIONMETAL-ORGANIC FRAMEWORKSCYCLOADDITION REACTIONSTRUCTURAL TRANSFORMATIONSPI-STACKINGISOMERIZATIONREACTIVITYGUESTMOLECULES

qrcode

Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.