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Moon, Hoi Ri
Functional Inorganic Nanomaterials for Energy Lab (FINE)
Research Interests
  • Inorganic-organic hybrid materials, carbon capture materials, hydrogen storage materials, heterogeneous catalyst

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Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand

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Title
Single-crystal-to-single-crystal transformation of a coordination polymer from 2D to 3D by [2 + 2] photodimerization assisted by a coexisting flexible ligand
Author
Lee, Jae HwaPark, SungbinJeoung, SungeunMoon, Hoi Ri
Issue Date
201707
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.19, no.27, pp.3719 - 3722
Abstract
A 2D interdigitated [Ni2(adipate)2(spy)4(H2O)2] (spy = 4-styrylpyridine) was transformed to a 3D coordination polymer through [2 + 2] photodimerization between the olefin bonds in spy upon UV-irradiation in a single-crystal-to-single-crystal (SC-SC) manner. During this transformation, a coexisting flexible adipate ligand changes its conformation, and helps in withstanding the conversion strain and retaining the single crystallinity.
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DOI
http://dx.doi.org/10.1039/c6ce02652d
ISSN
1466-8033
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