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DC Field | Value | Language |
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dc.citation.endPage | 6000 | - |
dc.citation.number | 25 | - |
dc.citation.startPage | 5994 | - |
dc.citation.title | CHEMISTRY-A EUROPEAN JOURNAL | - |
dc.citation.volume | 23 | - |
dc.contributor.author | Lastovickova, Dominika N. | - |
dc.contributor.author | Shao, Huiling | - |
dc.contributor.author | Lu, Gang | - |
dc.contributor.author | Liu, Peng | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-21T22:16:45Z | - |
dc.date.available | 2023-12-21T22:16:45Z | - |
dc.date.created | 2017-03-03 | - |
dc.date.issued | 2017-05 | - |
dc.description.abstract | A ring-opening metathesis polymerization catalyst supported by a redox-active N-heterocyclic carbene was synthesized and found to undergo reversible reduction. In its neutral form, the catalyst polymerized 1,5-cis,cis-cyclooctadiene at a higher rate than that of a norbornene derivative; however, upon reduction, the selectivity was found to reverse. Utilizing this oxidation state dependent selectivity, a series of copolymers with controlled compositions, microstructures, and physical properties were prepared by redox-switching the catalyst over the course of a series of polymerization reactions. | - |
dc.identifier.bibliographicCitation | CHEMISTRY-A EUROPEAN JOURNAL, v.23, no.25, pp.5994 - 6000 | - |
dc.identifier.doi | 10.1002/chem.201605738 | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.scopusid | 2-s2.0-85012071156 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/22003 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/chem.201605738/abstract | - |
dc.identifier.wosid | 000400580000022 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | A Ring-Opening Metathesis Polymerization Catalyst That Exhibits Redox-Switchable Monomer Selectivities | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | N-heterocyclic carbene | - |
dc.subject.keywordAuthor | olefin metathesis | - |
dc.subject.keywordAuthor | polymerization | - |
dc.subject.keywordAuthor | redox | - |
dc.subject.keywordAuthor | switchable | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENE | - |
dc.subject.keywordPlus | OLEFIN METATHESIS | - |
dc.subject.keywordPlus | RADICAL POLYMERIZATION | - |
dc.subject.keywordPlus | CYCLIC ESTERS | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | SEQUENCE | - |
dc.subject.keywordPlus | LIGANDS | - |
dc.subject.keywordPlus | LACTIDE | - |
dc.subject.keywordPlus | LIGHT | - |
dc.subject.keywordPlus | COPOLYMERIZATION | - |
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