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DC Field | Value | Language |
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dc.citation.endPage | 10625 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 10618 | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.volume | 9 | - |
dc.contributor.author | Palanisamy, Manikandan | - |
dc.contributor.author | Kim, Hyun Woo | - |
dc.contributor.author | Heo, Seongwoo | - |
dc.contributor.author | Lee, Eungje | - |
dc.contributor.author | Kim, Youngsik | - |
dc.date.accessioned | 2023-12-21T22:37:28Z | - |
dc.date.available | 2023-12-21T22:37:28Z | - |
dc.date.created | 2017-04-27 | - |
dc.date.issued | 2017-03 | - |
dc.description.abstract | Sodium-ion batteries are now close to replacing lithium-ion batteries because they provide superior alternative energy storage solutions that are in great demand, particularly for large-scale applications. To that end, the present study is focused on the properties of a new type of dual-electrode material, Na0.5Ni0.25Mn0.75O2, synthesized using a mixed hydroxycarbonate route. Cyclic voltammetry confirms that redox couples, at high and low voltage ranges, are facilitated by the unique features and properties of this dual-electrode, through sodium ion deintercalation/intercalation into the layered Na0.5Ni0.25Mn0.25O2 material. This material provides superior performance for Na-ion batteries, as evidenced by the fabricated sodium cell that yielded initial charge discharge capacities of 125/218 mAh g(-1) in the voltage range of 1.5-4.4 V at 0.5 C. At a low voltage range (1.5-2.6 V), the anode cell delivered discharge charge capacities of 100/99 mAh g(-1) with 99% capacity retention, which corresponds to highly reversible redox reaction of the Mn4+/3+ reduction and the Mn3+/4+ oxidation observed at 1.85 and 2.06 V, respectively. The symmetric Na-ion cell, fabricated using Na0.5Ni0.25Mn0.25O2, yielded initial charge discharge capacities of 196/187 mu Ah at 107 mu A. These results encourage the further development of new types of futuristic sodium-ion battery-based energy storage systems. | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES, v.9, no.12, pp.10618 - 10625 | - |
dc.identifier.doi | 10.1021/acsami.6b15355 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.scopusid | 2-s2.0-85016566900 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/21898 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/acsami.6b15355 | - |
dc.identifier.wosid | 000398246900035 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Insights into the Dual-Electrode Characteristics of Layered Na0.5Ni0.25Mn0.75O2 Materials for Sodium-Ion Batteries | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | mixed hydroxy-carbonate | - |
dc.subject.keywordAuthor | layered P2-type structure | - |
dc.subject.keywordAuthor | dual-electrode | - |
dc.subject.keywordAuthor | charge discharge cycling | - |
dc.subject.keywordAuthor | symmetric sodium-ion batteries | - |
dc.subject.keywordPlus | X LESS-THAN | - |
dc.subject.keywordPlus | HIGH-PERFORMANCE CATHODE | - |
dc.subject.keywordPlus | NICKEL-MANGANESE OXIDES | - |
dc.subject.keywordPlus | NA | - |
dc.subject.keywordPlus | INTERCALATION | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | P2-TYPE | - |
dc.subject.keywordPlus | CELL | - |
dc.subject.keywordPlus | PHASES | - |
dc.subject.keywordPlus | P3 | - |
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