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DC Field | Value | Language |
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dc.citation.endPage | 890 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 884 | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 50 | - |
dc.contributor.author | Kang, So-Huei | - |
dc.contributor.author | Lee, Hae Rang | - |
dc.contributor.author | Dutta, Gitish K. | - |
dc.contributor.author | Lee, Junghoon | - |
dc.contributor.author | Oh, Joon Hak | - |
dc.contributor.author | Yang, Changduk | - |
dc.date.accessioned | 2023-12-21T22:40:11Z | - |
dc.date.available | 2023-12-21T22:40:11Z | - |
dc.date.created | 2017-03-03 | - |
dc.date.issued | 2017-02 | - |
dc.description.abstract | The π-extended (E)-2-(2-(thiophen-2-yl)-vinyl)thiophene (TVT)-based polymers are an interesting class of semiconducting polymers because of their excellent mobilities and unique film microstructures. Despite these properties, the effect of the side-chain regiochemistry of TVT skeletons on the intrinsic properties of these polymers remains unclear. To investigate this, in this study, hexyl-substituted TVT subunits with a “tail in (TI)” or “tail out (TO)” regiosymmetrical arrangement were first introduced into diketopyrrolopyrrole (DPP)-based copolymer main chains to afford “isomeric” polymers PI and PO, respectively. By combining optical spectroscopy, atomic force microscopy (AFM), and grazing incidence X-ray diffraction (GIXD) data, we quantitatively characterized the aggregation, crystallization, and backbone orientation of both polymer films, which were then correlated to the charge-carrier mobilities. The PI film exhibited a bimodal packing motif comprising a mixture of edge-on and face-on orientations, which was beneficial for three-dimensional (3D) charge transport and resulted in a hole mobility 2-fold larger than that in the PO film (μh = 1.69 cm2 V-1 s-1). This comparative study substantiates the important role of the regiochemistry of TVT in developing high-performance semiconducting polymers. | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.50, no.3, pp.884 - 890 | - |
dc.identifier.doi | 10.1021/acs.macromol.6b02447 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.scopusid | 2-s2.0-85012986037 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/21560 | - |
dc.identifier.url | http://pubs.acs.org/doi/abs/10.1021/acs.macromol.6b02447 | - |
dc.identifier.wosid | 000394410200019 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | A Role of Side-Chain Regiochemistry of Thienylene-Vinylene-Thienylene (TVT) in the Transistor Performance of Isomeric Polymers | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | HIGH-MOBILITY | - |
dc.subject.keywordPlus | SOLAR-CELLS | - |
dc.subject.keywordPlus | CONJUGATED POLYMERS | - |
dc.subject.keywordPlus | ELECTRON-TRANSPORT | - |
dc.subject.keywordPlus | CHARGE-TRANSPORT | - |
dc.subject.keywordPlus | SEMICONDUCTORS | - |
dc.subject.keywordPlus | COPOLYMERS | - |
dc.subject.keywordPlus | MORPHOLOGY | - |
dc.subject.keywordPlus | DESIGN | - |
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