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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 11524 | - |
dc.citation.startPage | 11518 | - |
dc.citation.title | ORGANIC & BIOMOLECULAR CHEMISTRY | - |
dc.citation.volume | 14 | - |
dc.contributor.author | Jeon, Min Ho | - |
dc.contributor.author | Mathew, Bijoy P. | - |
dc.contributor.author | Kuram, Malleswara Rao | - |
dc.contributor.author | Myung, Kyungjae | - |
dc.contributor.author | Hong, Sung You | - |
dc.date.accessioned | 2023-12-21T23:06:33Z | - |
dc.date.available | 2023-12-21T23:06:33Z | - |
dc.date.created | 2016-12-07 | - |
dc.date.issued | 2016-12 | - |
dc.description.abstract | Here we report a straightforward cross-coupling method for the synthesis of non-natural glycoamino acids from alkyne-bearing monosaccharides and p-iodophenylalanine. Pd/Au-catalyzed Sonogashira coupling is tolerant to both O- and S-glycosides without any epimerization. In addition, no racemization of the amino acid was observed allowing direct access to the homogeneous glyco-conjugate in a single step. Notably, this Pd/Au catalytic system presents enhanced catalytic activity than conventional Pd/Cu and Pd-only platforms, and it further enables the convergent synthesis of glycodipeptides. | - |
dc.identifier.bibliographicCitation | ORGANIC & BIOMOLECULAR CHEMISTRY, v.14, pp.11518 - 11524 | - |
dc.identifier.doi | 10.1039/C6OB02437H | - |
dc.identifier.issn | 1477-0520 | - |
dc.identifier.scopusid | 2-s2.0-85004009084 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/20926 | - |
dc.identifier.url | http://pubs.rsc.org/en/content/articlelanding/2016/ob/c6ob02437h#!divAbstract | - |
dc.identifier.wosid | 000390471500025 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A palladium and gold catalytic system enables direct access to O- and S-linked non-natural glyco-conjugates | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | TERMINAL ALKYNES | - |
dc.subject.keywordPlus | CROSS-METATHESIS | - |
dc.subject.keywordPlus | PROTEINS | - |
dc.subject.keywordPlus | OLIGOSACCHARIDES | - |
dc.subject.keywordPlus | PHENYLALANINE | - |
dc.subject.keywordPlus | GLYCOBIOLOGY | - |
dc.subject.keywordPlus | ACTIVATION | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
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