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DC Field | Value | Language |
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dc.citation.endPage | 15005 | - |
dc.citation.number | 39 | - |
dc.citation.startPage | 14996 | - |
dc.citation.title | JOURNAL OF MATERIALS CHEMISTRY A | - |
dc.citation.volume | 4 | - |
dc.contributor.author | Jang, Ye-Ri | - |
dc.contributor.author | Kim, Ju-Myung | - |
dc.contributor.author | Lee, Jung-Han | - |
dc.contributor.author | Cho, Sung-Ju | - |
dc.contributor.author | Kim, Guntae | - |
dc.contributor.author | Ju, Young-Wan | - |
dc.contributor.author | Yeon, Sun-Hwa | - |
dc.contributor.author | Yoo, JongTae | - |
dc.contributor.author | Lee, Sang-Young | - |
dc.date.accessioned | 2023-12-21T23:10:22Z | - |
dc.date.available | 2023-12-21T23:10:22Z | - |
dc.date.created | 2016-10-21 | - |
dc.date.issued | 2016-10 | - |
dc.description.abstract | Formidable challenges facing lithium-ion rechargeable batteries, which involve performance degradations and safety failures during charge/discharge cycling, mostly arise from electrode-electrolyte interface instability. Here, as a polymeric ionic liquid (PIL)-mediated interfacial control strategy to address this long-standing issue, we demonstrate a new class of molecularly designed, ion/electron-conductive nanoshields based on single-walled carbon nanotube (SWCNT)-embedded, dual-doped mesoporous carbon (referred to as SMC) shells for electrode materials. The SMC shell is formed on cathode materials through solution deposition of the SWCNT/PIL mixture and subsequent carbonization. The PIL (denoted as PVIm[DS]) synthesized in this study consists of poly(1-vinyl-3-ethylimidazolium) cations and dodecyl sulfate counter anions, whose molecular structures are rationally designed to achieve the following multiple functions: (i) precursor for the conformal/continuous nanothickness carbon shell, (ii) dual (N and S)-doping source, (iii) porogen for the mesoporous structure, and (iv) SWCNT dispersant. Driven by such chemical/structural uniqueness, the SMC shell prevents direct exposure of cathode materials to bulk liquid electrolytes while facilitating redox reaction kinetics. As a consequence, the SMC-coated cathode materials enable significant improvements in cell performance and also thermal stability. We envision that the SMC shell can be suggested as a new concept of effective and versatile surface modification strategy for next-generation high-performance electrode materials. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MATERIALS CHEMISTRY A, v.4, no.39, pp.14996 - 15005 | - |
dc.identifier.doi | 10.1039/c6ta06666f | - |
dc.identifier.issn | 2050-7488 | - |
dc.identifier.scopusid | 2-s2.0-84990196653 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/20727 | - |
dc.identifier.url | http://pubs.rsc.org/en/Content/ArticleLanding/2016/TA/C6TA06666F#!divAbstract | - |
dc.identifier.wosid | 000386700600014 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRYROYAL SOC CHEMISTRY | - |
dc.title | Molecularly designed, dual-doped mesoporous carbon/SWCNT nanoshields for lithium battery electrode materials | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Energy & Fuels; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | ION BATTERIES | - |
dc.subject.keywordPlus | CATHODE MATERIALS | - |
dc.subject.keywordPlus | POLYMER ELECTROLYTES | - |
dc.subject.keywordPlus | PERFORMANCE | - |
dc.subject.keywordPlus | LIQUIDS | - |
dc.subject.keywordPlus | LI4TI5O12 | - |
dc.subject.keywordPlus | REDUCTION | - |
dc.subject.keywordPlus | PRECURSOR | - |
dc.subject.keywordPlus | STORAGE | - |
dc.subject.keywordPlus | SULFUR | - |
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