There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 2596 | - |
dc.citation.number | 29 | - |
dc.citation.startPage | 2588 | - |
dc.citation.title | JOURNAL OF COMPUTATIONAL CHEMISTRY | - |
dc.citation.volume | 37 | - |
dc.contributor.author | Hu, Ming Xing | - |
dc.contributor.author | Xu, Tianlv | - |
dc.contributor.author | Momen, Roya | - |
dc.contributor.author | Huan, Guo | - |
dc.contributor.author | Kirk, Steven R. | - |
dc.contributor.author | Jenkins, Samantha | - |
dc.contributor.author | Filatov, Mechael | - |
dc.date.accessioned | 2023-12-21T23:08:13Z | - |
dc.date.available | 2023-12-21T23:08:13Z | - |
dc.date.created | 2016-11-04 | - |
dc.date.issued | 2016-11 | - |
dc.description.abstract | The utility of the QTAIM/stress tensor analysis method for characterizing the photoisomerization of light driven molecular rotary machines is investigated on the example of the torsion path in fluorene molecular motor. The scalar and vector descriptors of QTAIM/stress tensor reveal additional information on the bonding interactions between the rotating units of the motor, which cannot be obtained from the analysis of the ground and excited state potential energy surfaces. The topological features of the fluorene motor molecular graph display that, upon the photoexcitation a certain increase in the torsional stiffness of the rotating bond can be attributed to the increasing topological stability of the rotor carbon atom attached to the rotation axle. The established variations in the torsional stiffness of the rotating bond may cause transfer of certain fraction of the torsional energy to other internal degrees of freedom, such as the pyramidalization distortion. | - |
dc.identifier.bibliographicCitation | JOURNAL OF COMPUTATIONAL CHEMISTRY, v.37, no.29, pp.2588 - 2596 | - |
dc.identifier.doi | 10.1002/jcc.24487 | - |
dc.identifier.issn | 0192-8651 | - |
dc.identifier.scopusid | 2-s2.0-84992206106 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/20672 | - |
dc.identifier.url | http://onlinelibrary.wiley.com/doi/10.1002/jcc.24487/abstract | - |
dc.identifier.wosid | 000387484700004 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-BLACKWELL | - |
dc.title | A QTAIM and stress tensor investigation of the torsion path of a light-driven fluorene molecular rotary motor | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | photoisomerization | - |
dc.subject.keywordAuthor | light driven molecular rotary machine | - |
dc.subject.keywordAuthor | QTAIM | - |
dc.subject.keywordAuthor | stress tensor | - |
dc.subject.keywordPlus | DENSITY-FUNCTIONAL THEORY | - |
dc.subject.keywordPlus | REFERENCED KOHN-SHAM | - |
dc.subject.keywordPlus | CONICAL INTERSECTIONS | - |
dc.subject.keywordPlus | EXCITED-STATES | - |
dc.subject.keywordPlus | ELECTRONIC-STRUCTURE | - |
dc.subject.keywordPlus | QUANTUM TOPOLOGY | - |
dc.subject.keywordPlus | HYDROGEN-BOND | - |
dc.subject.keywordPlus | DYNAMICS | - |
dc.subject.keywordPlus | PHOTOISOMERIZATION | - |
dc.subject.keywordPlus | ATOMS | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.