Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.number | 9 | - |
dc.citation.startPage | 141 | - |
dc.citation.title | CATALYSTS | - |
dc.citation.volume | 6 | - |
dc.contributor.author | Lastovickova, Dominika N. | - |
dc.contributor.author | Bielawski, Christopher W. | - |
dc.date.accessioned | 2023-12-21T23:13:13Z | - |
dc.date.available | 2023-12-21T23:13:13Z | - |
dc.date.created | 2016-10-07 | - |
dc.date.issued | 2016-09 | - |
dc.description.abstract | An isolable N,N′-diamidocarbene (DAC) was previously shown to promote the B-H bond activation of various BH3 complexes. The resultant DAC-BH3 adducts facilitated olefin hydroborations under mild conditions and in the absence of exogenous initiators. The substrate scope for such transformations was further explored and is described herein. While organoboranes were obtained in quantitative yields from various terminal and internal olefins, use of the latter substrates resulted in intramolecular ring-expansion of the newly formed DAC-borane adducts. | - |
dc.identifier.bibliographicCitation | CATALYSTS, v.6, no.9, pp.141 | - |
dc.identifier.doi | 10.3390/catal6090141 | - |
dc.identifier.issn | 2073-4344 | - |
dc.identifier.scopusid | 2-s2.0-84988432768 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/20556 | - |
dc.identifier.url | http://www.mdpi.com/2073-4344/6/9/141 | - |
dc.identifier.wosid | 000384675300015 | - |
dc.language | 영어 | - |
dc.publisher | MDPI AG | - |
dc.title | Olefin hydroborations with diamidocarbene-BH3 adducts at room temperature | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | hydroboration | - |
dc.subject.keywordAuthor | carbenes | - |
dc.subject.keywordAuthor | organocatalysis | - |
dc.subject.keywordAuthor | Lewis adducts | - |
dc.subject.keywordAuthor | diamidocarbene | - |
dc.subject.keywordPlus | N-HETEROCYCLIC CARBENES | - |
dc.subject.keywordPlus | CHEMICAL-SHIFTS | - |
dc.subject.keywordPlus | H ACTIVATION | - |
dc.subject.keywordPlus | BORANE | - |
dc.subject.keywordPlus | HYDROGEN | - |
dc.subject.keywordPlus | ORGANOBORANES | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | AMMONIA | - |
dc.subject.keywordPlus | ALKENES | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.