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곽상규

Kwak, Sang Kyu
Kyu’s MolSim Lab @ UNIST
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DC Field Value Language
dc.citation.endPage 1925 -
dc.citation.number 4 -
dc.citation.startPage 1920 -
dc.citation.title INORGANIC CHEMISTRY -
dc.citation.volume 55 -
dc.contributor.author Hyun, Sung-min -
dc.contributor.author Lee, Jae Hwa -
dc.contributor.author Jung, Gwan Yeong -
dc.contributor.author Kim, Yun Kyeong -
dc.contributor.author Kim, Tae Kyung -
dc.contributor.author Jeoung, Sungeun -
dc.contributor.author Kwak, Sang Kyu -
dc.contributor.author Moon, Dohyun -
dc.contributor.author Moon, Hoi Ri -
dc.date.accessioned 2023-12-22T00:13:46Z -
dc.date.available 2023-12-22T00:13:46Z -
dc.date.created 2016-02-02 -
dc.date.issued 2016-01 -
dc.description.abstract Flexible metal-organic frameworks (MOFs) show the structural transition phenomena, gate opening and breathing, upon the input of external stimuli. These phenomena have significant implications in their adsorptive applications. In this work, we demonstrate the direct capture of these gate-opening and breathing phenomena, triggered by CO2 molecules, in a well-designed flexible MOF composed of rotational sites and molecular gates. Combining X-ray single crystallographic data of a flexible MOF during gate opening/closing and breathing with in situ X-ray powder diffraction results uncovered the origin of this flexibility. Furthermore, computational studies revealed the specific sites required to open these gates by interaction with CO2 molecules. -
dc.identifier.bibliographicCitation INORGANIC CHEMISTRY, v.55, no.4, pp.1920 - 1925 -
dc.identifier.doi 10.1021/acs.inorgchem.5b02874 -
dc.identifier.issn 0020-1669 -
dc.identifier.scopusid 2-s2.0-84958758020 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/18383 -
dc.identifier.url http://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.5b02874 -
dc.identifier.wosid 000370395000065 -
dc.language 영어 -
dc.publisher AMER CHEMICAL SOC -
dc.title Exploration of Gate-Opening and Breathing Phenomena in a Tailored Flexible Metal-Organic Framework -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Chemistry, Inorganic & Nuclear -
dc.relation.journalResearchArea Chemistry -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordPlus POROUS COORDINATION-POLYMER -
dc.subject.keywordPlus GAS-ADSORPTION -
dc.subject.keywordPlus SINGLE-CRYSTAL -
dc.subject.keywordPlus CARBON-DIOXIDE -
dc.subject.keywordPlus CO2 ADSORPTION -
dc.subject.keywordPlus SELECTIVE ADSORPTION -
dc.subject.keywordPlus GUEST MOLECULES -
dc.subject.keywordPlus MIL-53 -
dc.subject.keywordPlus TRANSFORMATION -
dc.subject.keywordPlus SIMULATIONS -

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