JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, v.41, no.16, pp.2502 - 2511
Abstract
Four different types of conjugated copolymers, consisting of alternating structures of phenothiazinylene vinylene and phenylene vinylene derivatives such as phenylene vinylene, 1,1'-biphenyl-4,4'-ylene vinylene, 2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene vinylene, and 9,10-anthrylene vinylene, were prepared by Horner-Emmons condensation between appropriate diphosphonates and dialdehydes. Single-layer and double-layer light-emitting diodes were fabricated with the synthesized conjugated polymers, and their electroluminescent properties were investigated. Poly(N-2-ethylhexyl-3,6-phenothiazinylene vinylene-alt-9,10-anthrylene vinylene), containing phenothiazinylene vinylene and anthrylene vinylene as repeat units, emitted a reddish-orange color with Commission Internationale de l'Eclairage coordinates of x = 0.6173 and y = 0.3814 that was very similar to the National Television System Committee standard red, and it showed a bipolar carrier-injection/transporting capability caused by electron-withdrawing anthracene and electron-donating amino groups. Poly[N-2-ethylhexyl-3,6-phenothiazinylene vinylene-alt-2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylene vinylene], containing phenothiazinylene vinylene and dialkoxy phenylene vinylene moieties, showed excellent hole-injection/transporting capability. (C) 2003 Wiley Periodicals, Inc