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DC Field | Value | Language |
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dc.citation.endPage | 99 | - |
dc.citation.startPage | 95 | - |
dc.citation.title | CATALYSIS TODAY | - |
dc.citation.volume | 260 | - |
dc.contributor.author | Bernardi, Fabiano | - |
dc.contributor.author | Grass, Michael E. | - |
dc.contributor.author | Hong, Young P. | - |
dc.contributor.author | Chang, Rui | - |
dc.contributor.author | Jabeen, Naila | - |
dc.contributor.author | Zhang, Chunjuan | - |
dc.contributor.author | Eichhorn, Bryan W. | - |
dc.contributor.author | Seo, Bora | - |
dc.contributor.author | Alayoglu, Selim | - |
dc.contributor.author | Hussain, Zahid | - |
dc.contributor.author | Joo, Sang Hoon | - |
dc.contributor.author | Liu, Zhi | - |
dc.date.accessioned | 2023-12-22T00:11:13Z | - |
dc.date.available | 2023-12-22T00:11:13Z | - |
dc.date.created | 2015-09-04 | - |
dc.date.issued | 2016-02 | - |
dc.description.abstract | Rh0.5Pd0.5/CeO2 bimetallic nanoparticles were subjected to reducing and oxidizing atmospheres at different temperatures and characterized by means of the Ambient Pressure X-Ray Photoelectron Spectroscopy (AP-XPS). The surface atomic population is calculated for all cases. By using a high temperature pretreatment at 480 degrees C in H-2 atmosphere, it was possible to control the surface atomic population with Pd atoms frozen at the skin layer even in an oxidizing atmosphere, which is not observed without high temperature pre-treatment (Rh atoms at the skin layer). The change of the Rh/Pd surface segregation behavior after the high temperature pre-treatment is attributed to the geometrical factor of Strong Metal Support Interaction (SMSI) effect, i.e., the occurrence of the ceria capping layer around nanoparticles. | - |
dc.identifier.bibliographicCitation | CATALYSIS TODAY, v.260, pp.95 - 99 | - |
dc.identifier.doi | 10.1016/j.cattod.2015.06.024 | - |
dc.identifier.issn | 0920-5861 | - |
dc.identifier.scopusid | 2-s2.0-84947870228 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/16647 | - |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S0920586115003910 | - |
dc.identifier.wosid | 000364865800015 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER SCIENCE BV | - |
dc.title | Control of the surface atomic population of Rh |
- |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Applied; Chemistry, Physical; Engineering, Chemical | - |
dc.relation.journalResearchArea | Chemistry; Engineering | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Strong metal support interaction | - |
dc.subject.keywordAuthor | Bimetallic nanoparticles | - |
dc.subject.keywordAuthor | AP-XPS | - |
dc.subject.keywordAuthor | RhPd | - |
dc.subject.keywordAuthor | CeO2 | - |
dc.subject.keywordPlus | RAY PHOTOELECTRON-SPECTROSCOPY | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | SEGREGATION | - |
dc.subject.keywordPlus | OXIDE | - |
dc.subject.keywordPlus | CERIA | - |
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