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- Lee, Jae Sung
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Band gap tuning of lead-substituted BaSnO3 for visible light photocatalysis
- Alternative Title
- Band gap tuning of lead-substituted BaSnO3 for visible light photocatalysis
- Author(s)
- Borse, Pramod H., Joshi, Upendra A., Ji, Sang Min, Jang, Jum Suk, Lee, Jae Sung, Jeong, Euh Duck, Kim, Hyun Gyu
- Issued Date
- 2007-01
- Citation
- APPLIED PHYSICS LETTERS, v.90, no.3, pp.034103
- Abstract
- The Pb substitution effect was investigated experimentally and theoretically on the crystal structure of BaSnO3 and on the photo-oxidation activity of H2O. The chemically doped Pb in BaSnO3 induced a concentration-dependent redshift of the experimental band gap (BG). The BaPb0.8Sn0.2O3 system produced 32 mu mol/h of O-2 under lambda >= 420 nm photons, but no O-2 for BaSnO3. The DFT calculations of BaPbxSn1-xO3 (x=0,0.5,1) by using generalized approximation, implying the BG alteration and the photocatalytic activity of BaPbxSn1-xO3, are due to the induced Pb 6s orbital in the BG of BaSnO3. Thus Pb modified the insulating nature of BaSnO3 to semiconducting and semimetallic. (c) 2007 American Institute of Physics
- Publisher
- AMER INST PHYSICS
- ISSN
- 0003-6951
- Keyword
- WATER
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