File Download
There are no files associated with this item.
SFX Link
- Find it @ UNIST can give you direct access to the published full text of this article. (UNISTARs only)
- Lee, Jae Sung
- Eco-friendly Catalysis & Energy Lab.
Views & Downloads
Detailed Information
Cited time in 
Cited time in 
Cited time in
Metadata Downloads
Coupled oxidative carbonylation of bisphenol-A and phenol into phenylcarbonate-ended polycarbonate precursors over a homogeneous Pd-Ce redox catalyst
- Alternative Title
- Coupled oxidative carbonylation of bisphenol-A and phenol into phenylcarbonate-ended polycarbonate precursors over a homogeneous Pd-Ce redox catalyst
- Author(s)
- Kim, Won Bae, Park, Kuang Ho, Lee, Jae Sung
- Issued Date
- 2002-06
- Citation
- JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, v.184, no.1-2, pp.39 - 49
- Abstract
- A coupled oxidative carbonylation of bisphenol-A and phenol was investigated using a redox catalytic system of palladium acetate and cerium acetate as a novel scheme for a direct synthesis of phenylcarbotiate-ended polycarbonate precursors amenable to polycondensation in a current phosgene-free polycarbonate process. Reaction variables such as solvents, bases and organic co-catalysts were examined in our novel scheme. Removal of water co-produced with desired products and adjustment of the reactants molar ratio of phenol to bisphenol-A appeared to be most critical for highly selective formation of the desired phenylcarbonate-ended precursors in one-step. (C) 2002 Elsevier Science B.V. All rights reserved
- Publisher
- ELSEVIER SCIENCE BV
- ISSN
- 1381-1169
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.