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N-doped double-walled carbon nanotubes synthesized by chemical vapor deposition

Alternative Title
N-doped double-walled carbon nanotubes synthesized by chemical vapor deposition
Author(s)
Kim, Shin YoungLee, JinyoungNa, Chan WoongPark, JeungheeSeo, KwanyongKim, Bongsoo
Issued Date
2005-09
DOI
10.1016/j.cplett.2005.07.093
URI
https://scholarworks.unist.ac.kr/handle/201301/12261
Fulltext
http://www.sciencedirect.com/science/article/pii/S0009261405011334
Citation
CHEMICAL PHYSICS LETTERS, v.413, no.4-6, pp.300 - 305
Abstract
High-purity N-doped double-walled carbon nanotubes (DWNTs) were synthesized by chemical vapor deposition, and investigated by synchrotron X-ray photoelectron spectroscopy (XPS). As the photon energy increases, the N content increases up to 3 at.%, indicating that the inner wall contains the higher N content than the outer wall. The graphite-like and pyridine-like N structures exist as about 1:1 ratio. The self-consistent charge-density-functional-based tight-binding calculation shows that the N-doping of the inner wall yields the more stable DWNT than that of the outer wall, which supports the XPS result. (c) 2005 Elsevier B.V. All rights reserved
Publisher
ELSEVIER SCIENCE BV
ISSN
0009-2614
Keyword
RAY PHOTOELECTRON-SPECTROSCOPYELECTRONIC-STRUCTURERAMAN-SCATTERINGARC-DISCHARGENITROGENBUNDLESNITRIDEGROWTH

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