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Schultz, Thomas
CRASY(Correlated Rotational Alignment Spectroscopy)
Research Interests
  • Correlated spectroscopy

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CRASY: Correlated rotational alignment spectroscopy reveals atomic scrambling in ionic states of butadiene

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Title
CRASY: Correlated rotational alignment spectroscopy reveals atomic scrambling in ionic states of butadiene
Author
Schroter, ChristianChoi, Chang MinSchultz, Thomas
Keywords
Ionic state; Isotopologues; Rotational alignment
Issue Date
201502
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF PHYSICAL CHEMISTRY A, v.119, no.8, pp.1309 - 1314
Abstract
We use correlated rotational alignment spectroscopy to reveal atomic scrambling in transient ionic states of butadiene. Investigating a natural sample, we assign signals of two trans-1,3-butadiene isotopologues that contain a single 13C isotope and quantify the fragment abundance for the 13CH3 loss channel for each isotopologue. © 2015 American Chemical Society
URI
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DOI
http://dx.doi.org/10.1021/jp511579z
ISSN
1089-5639
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